[1,5-Bis(4-fluorophenyl)thiocarbazonato-κ2N5,S]phenylmercury(II) dichloromethane hemisolvate
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چکیده
منابع مشابه
Bis{μ-2-[(dimethylamino)methyl]benzeneselenolato}bis[chloridopalladium(II)] dichloromethane hemisolvate
The asymmetric unit of the title compound, [Pd(2)(C(9)H(12)NSe)(2)Cl(2)]·0.5CH(2)Cl(2), contains two half-mol-ecules, each lying on a twofold axis; each mol-ecule is chiral and of the same enanti-omer. This is only possible as the mol-ecule has a hinged cis arrangement about the Pd(2+) coordination spheres. For this hinged dimeric structure, the angles between the two coordination planes in eac...
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In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inv...
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A 47-year-old man was found dead in a factory where dichloromethane (DCM) tanks were stocked. He was making an inventory of the annual stock of DCM contained in several tanks (5- to 8000-L capacity) by transferring the solvent into an additional tank with the help of compressed air. During this operation, one of the tanks overflowed and the man, who was not wearing any protection, was intoxicat...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811050331